In recent years, there has been a growing interest in video Photoplethysmography (vPPG), a technique able to estimate cardiovascular parameters from video recordings of the skin. Despite the growing interest in vPPG technology, there are still problems in extracting the correct waveform of blood volume pulse, mainly due to real world artifacts, such as changes in light condition and movement artifacts. Another important issue is the correct definition of skin against background. Therefore, we propose an algorithm of skin detection that is able to recognize skin pixels solid to variations of luminosity. We recorded the signals of interest during an experimental protocol designed to provide thermal stimulation and observe the resulting Autonomic Nervous System changes. Experimental data were gathered from 10 young healthy subjects (age: 21+/-2 years). Video recordings are processed using a band-pass filter and then an automatic algorithm of peak detection is applied to detect the pulse wave peaks, then used to estimate heart rate variability (HRV). The efficiency and stability of the algorithm are compared against finger-PPG waveforms. Preliminary results show an overall statistical agreement between time and frequency domain indexes. However, further efforts are required to improve the estimation of frequency components, particularly during rest.